Substituent Effects. XX. Highly Electron-Deficient Carbocation Solvolyses
نویسندگان
چکیده
منابع مشابه
β-Hydroxy carbocation intermediates in solvolyses of di- and tetra-hydronaphthalene substrates
Solvolysis of trichloroacetate esters of 2-methoxy-1,2-dihydro-1-naphthols shows a remarkably large difference in rates between the cis and trans isomers, k(cis)/k(trans) = 1800 in aqueous acetonitrile. This mirrors the behaviour of the acid-catalysed dehydration of cis- and trans-naphthalene-1,2-dihydrodiols to form 2-naphthol, for which k(cis)/k(trans) = 440, but contrasts with that for solvo...
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متن کاملSecondary Deuterium Isotope Effects in Solvolyses of Small-ring Compounds.
M.I.T. Quart. Prog. Rept., 50, 11 (1963); (f) McLean, A. D., J. Chem. Phys., 32, 1959 (1960). 6 Clementi, E., C. Roothaan, and M. Yoshimine, Phys. Rev., 127, 1618 (1962). 7K = 1.75, a(2s)= -0.559 au; a(2p)= -0.312 au; a(H) -0.50 au. 8 For BH a(2s) = -0.909 au; a(2p) = -0.314 au; a(H) = -0.591 au. For BB a(2s) -0.920 au; a(2pr) = -0.189 au; a(2pir) = -0.179 au. 9 Newton, M. D., unpublished work....
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1990
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.63.1138